Posts tagged Saltwater
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Aquarium filters are critical components of both freshwater and marine aquaria. Aquarium filters remove physical and soluble chemical waste products from aquaria simplifying maintenance. Furthermore, aquarium filters are necessary to support life as aquaria are relatively small, closed volumes of water compared to the natural environment of most fish.
Animals, typically fish, kept in fish tanks produce waste from excrement and respiration. Another source of waste is uneaten food or plants and fish which have died. These waste products collect in the tanks and contaminate the water. As the degree of contamination rises, the risk to the health of the aquaria increases and removal of the contamination becomes critical. Filtration is a common method used for maintenance of healthy aquaria.
 Biological filtration and the nitrogen cycle
Proper management of the nitrogen cycle is a vital element of a successful aquarium. Excretia and other decomposing organic matter produce ammonia which is highly toxic to fish. Bacterial processes oxidize this ammonia into the slightly less toxic nitrites, and these are in turn oxidized to form the much less toxic nitrates. In the natural environment these nitrates are subsequently taken up by plants as fertilizer and this does indeed happen to some extent in an aquarium planted with real plants.
An aquarium is, however, an imperfect microcosm of the natural world. Aquariums are usually much more densely stocked with fish than the natural environment. This increases the amount of ammonia produced in the relatively small volume of the aquarium. The bacteria responsible for breaking down the ammonia colonize the surface of any objects inside the aquarium. A biological filter is nothing more than a chemically inert porous sponge, which provides a greatly enlarged surface area on which these bacteria can develop. These bacterial colonies take several weeks to form, during which time the aquarium is vulnerable to a condition commonly known as “new tank syndrome” if stocked with fish too quickly. Accumulation of toxic ammonia from decomposing wastes is the largest cause of fish mortality in new, poorly maintained or overloaded aquariums. In the artificial environment of the aquarium, the nitrogen cycle effectively ends with the production of nitrates. In order that the nitrate level does not build up to a harmful level regular partial water changes are required to remove the nitrates and introduce new, uncontaminated water.
 Mechanical and chemical filtration
The process of mechanical filtration removes particulate material from the water column. This particulate matter may include uneaten food, faeces or plant or algal debris. Mechanical filtration is typically achieved by passing water through materials which act as a sieve, physically trapping the particulate matter. Removal of solid waste can be as simple as physical hand netting of debris, and/or involve highly complex equipment. All removal of solid wastes involve filtering water through some form of mesh in a process known as mechanical filtration. The solid wastes are first collected, and then must be physically removed from the aquarium system. Mechanical filtration is ultimately ineffective if the solid wastes are not removed from the filter, and are allowed to decay and dissolve in the water.
Dissolved wastes are more difficult to remove from the water. Several techniques, collectively known as chemical filtration, are used for the removal of dissolved wastes, the most popular being the use of activated carbon and foam fractionation. To a certain extent, healthy plants extract dissolved chemical wastes from water when they grow, so plants can serve a role in the containment of dissolved wastes.
A final and less common situation requiring filtration involves the desire to sterilize water born pathogens. This sterilization is accomplished by passing aquarium water through filtration devices which expose the water to high intensity ultraviolet light and/or exposing the water to dissolved ozone gas.
 Materials suitable for aquarium filtration
Numerous materials are suitable as aquarium filtration media. These include synthetic wools, known in the aquarium hobby as filter wool, made of polyethylene terephthalate or nylon. Synthetic sponges or foams, various ceramic and sintered glass and silicon products along with igneous gravels are also used as mechanical filter materials. Materials with a greater surface area provide both mechanical and biological filtration. Some filter materials, such as plastic “bioballs”, are best used for biological filtration.
With the notable exception of diatom filters, aquarium filters are rarely purely mechanical in action, as bacteria will colonise most filter materials effecting some degree of biological filtration. Activated carbon and zeolites are also frequently added to aquarium filters. These highly porous materials act as adsorbates binding various chemicals to their large external surfaces and also as sites of bacterial colonisation.
The simplest type of aquarium filter consists only of filter wool and activated carbon. The filter wool traps large debris and particles, and the activated carbon adsorbs smaller impurities. These should be changed regularly at suitable intervals. This is particularly important in the case of activated carbon filters, which may re-release their adsorbed contents in large (and therefore harmful) doses if they are allowed to saturate. 
 Types of aquarium filters
Numerous types of aquarium filters are commercially available, including:
 External filters
External filters remove water from the aquarium which is then pushed (or pulled) through a series of different levels filter media and returned to the aquarium. They are usually more effective and easier to maintain than internal filters.
 Canister filters
Compared to filters that hang on the back of the aquarium, canister-style external filters offer a greater quantity of filter materials to be used along with a greater degree of flexibility with respect to filter material choice. Water enters the canister filled with the chosen filter material through an intake pipe at the bottom of the canister, passes through the material, and is pumped back to the aquarium through an electric pump on the top of the canister. Benefits of this type of filter are that they can provide a high volume of filter material without reducing the internal space in the aquarium, and that they can be disconnected from the tank for cleaning/maintenance and replaced without disturbing the aquarium interior or occupants. Disadvantages of canister filters include the increased cost and complexity relative to internal filters and difficulties in cleaning the tubes which transfer water to and from the aquarium. There’s also the risk of a leak, which naturally is an issue for any filter placed outside of the aquarium.
 Diatom filters
Diatom filters are used only for sporadic cleaning of tanks, they are not continuously operated on aquariums. These filters utilise diatomaceous earth to create an extremely fine filter down to 1 µm which removes particulate matter from the water column.
 Trickle filters
Trickle filters, also known as wet/dry filters are another water filtration systems for marine and freshwater aquariums. This filter comes in two configurations, one which is placed on top of the aquarium (more rarely seen) and one which is placed below the aquarium (more common).
If the wet/dry filter is placed on top of the aquarium, water is pumped over a number of perforated trays containing filter wool or some other filter material. The water trickles through the trays, keeping the filter wool wet but not completely submerged, allowing aerobic bacteria to grow and aiding biological filtration. The water returns to the aquarium like rain.
Alternatively, the wet/dry filter may be placed below the tank. In this design, water is fed by gravity to the filter below the aquarium. Prefiltered water is delivered to a perforated plate (drip plate). Prefiltering may take place in the aquarium via a foam block or sleeve in the overflow, or weir siphon, or it may be prefiltered by filter wool resting on the perforated plate. The waste laden water from the aquarium spreads over the drip plate, and rains down through a medium. This may be a filter wool/plastic grid rolled into a circular shape (DLS or “Double Layer Spiral”) or any number of plastic media commonly known as Bio Balls. As the water cascades over the media, CO2 is given off, oxygen is picked up, and bacteria convert the waste from the tank into less harmful materials. From here the water enters the sump. The sump may contain a number of compartments, each with its own filtration material. Often, heaters and thermostats are placed in the sump.
 Baffle filters
Baffle filters are similar to wet and dry, trickle filters in that they are generally situated below the aquarium. This type of filter consists of a series of baffles that the water must pass through in order to reach the pump which is returning water to the aquarium. These baffles then act much like a series of canister filters and can be filled with different filter media for different purposes..
 Internal filters
Internal filters are, by definition, filters within the confines of the aquarium. These include the sponge filter, variations on the corner filter (pictured top right and left), foam cartridge filter and the undergravel filter. An internal filter may have an electric pump and thus be an internal power filter, often attached to the inside of aquaria via suction cups.
 Airlift filters
Sponge filters and corner filters (sometimes called box filters) work by essentially the same mechanism as an internal filter. Both generally work by airlift, using bubbles from an air pump rising in a tube to create flow. In a sponge filter, the inlet may only be covered by a simple open-cell block of foam. A corner filter is slightly more complex. These filters are oftenplaced in the corner on the bottom of the aquarium. Water enters slits in the box, passes through a layer of medium, then exits through the airlift tube to return to the aquarium. These filters tend to only be suitable for small and lightly-stocked aquaria. The sponge filter is especially useful for rearing fry where the sponge prevents the small fish from entering the filter.
 Undergravel filters
Undergravel filters consist of a porous plate which is placed beneath the gravel on the base of the aquarium and one, or more, uplift tubes. Historically, undergravel filters have been driven via air displacement. Air stones are placed at the base of uplift tubes which force water out of the uplift tube creating negative pressure beneath the undergravel filter plate. Water then percolates down through the gravel which itself is the filtration material. Greater flow rate of water through the gravel can be achieved via the use of water pump rather than air displacement.
Undergravel filters can be detrimental to the health of aquatic plants. Fine substrates such as sand or peat may clog an undergravel filter. Undergravel filters are not effective if the substrate bed is uneven. In an uneven gravel bed, water will flow only through the thin portions of the bed, leaving the more heavily covered areas to become anoxic. Because of this, animals that dig, such as cichlids, are best kept in an aquarium using some other type of filtration.
 Submersible pumps/filters
or circulation pumps
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 Marine-specific systems
Marine aquaria have specialised needs and requirements, to this end the filtration of the marine aquarium is often more complex than freshwater aquariums.
 Protein Skimmers
Protein skimmers are filters used to fractionate and remove various dissolved organic contaminates typically from marine aquariums. The technique uses the chemical polarity of proteins and amino acids to remove the compounds in the foam produced by the filter. As very fine air bubbles are introduced into the fractionating column, the organic compounds attach to the bubbles. The air bubbles rise, and collect at the top of the Protein Skimmer, coagulating into a stiffer foam. The foam eventually builds up and overflows into a collection cup for complete removal. This is beneficial because the contaminates are removed from the system prior to decomposition into more toxic compounds. Protein skimmers are often used in combination with other filtration devices in marine aquarium setups.
 Deep sand beds
 Berlin method
The Berlin method of marine tank filtration is similar to the deep sand bed filtration technique in that relies on the action of anaerobic bacteria in the outer layers of porous rocks to degrade nitrate to gaseous nitrogen.
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